Product ID:P4671 PYRENONE CONCENTRATE
MSDS Date:09/22/1989
FSC:6850
NIIN:00F045563
MSDS Number: BYLTK

VAN WATERS & ROGERS INC SUB OF UNIVAR

6100 CARILLON POINT
KIRKLAND, WA 98033-5000
US

Emergency Phone: 206-889-3400

Info Phone: 206-889-3400

Cage: DO735

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

LPA SOLVENT VISTA

Fraction By Weight: 68-98%

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *95-4*

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 13%

OSHA PEL 260 MG/CUM

ACGIH TLV: 262 MG/CUM (SKIN)

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *95-4*

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 15%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM, SKIN

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ALKYL ARYL SULFONATE

Fraction By Weight: 17%

NONIONIC SURFACTANT

Fraction By Weight: 55%

PYRETHRINS (PYRENONE) *95-4*

CAS: 8003-34-7

RTECS: UR4200000

Fraction By Weight: 1.7-18%

OSHA PEL 5 MG/CUM

ACGIH TLV: 5 MG/CUM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

PIPERONYL BUTOXIDE

CAS: 51-03-6

RTECS: XS8050000

Fraction By Weight: 53.07%

MIXTURE OF C*13-C*17 HYDROCARBONS

Fraction By Weight: 41.63%

ATLOX 1045A

Fraction By Weight: 0-15%

LD50 LC50 Mixture:ORAL LD50 (RAT): 39.9 G/KG LPA SOLVENT
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: NOSE & THROAT IRRITATION.
EYES: IRRITATION. SKIN: IRRITATION, DERMATITIS. MAY BE ABSORBED TO
CAUSE SYSTEMIC EFFECTS INCLUDING OPTIC NEURITIS. INGESTION: IF
VOMITING OCCURS SPONTANEOUSLY, D ON'T ALLOW VOMITUS TO INTER LUNGS,
MAY CAUSE CHEMICAL PNEUMONITIS & PULMONARY EDEMA/HEMORRHAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHES, NAUSEA, VOMITING, COMA,
UNCONSCIOUSNESS, DEATH, BLURRED VISION, COMPLETE BLINDNESS.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. EYES:
IMMEDIATELY FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER.
INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY,
KEEP HE AD BELOW HIPS TO PREVENT THE VOMITUS INTO THE LUNGS. OBTAIN
MEDICAL ATTENTION IN ALL CASES.

Flash Point Method:CC
Flash Point:>100F
Extinguishing Media:USE DRY CHEMICAL, CO2/ALCOHOL FOAM. DON'T USE WATER
TO FIGHT FIRE.
Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING. USE
WATER SPRAY TO COOL NEARBY CONTAINERS & STRUCTURES.
Unusual Fire/Explosion Hazard:EXTINGUISH NEARBY IGNITION SOURCES.
VAPORS ARE >THAN AIR & MAY TRAVEL TO IGNITION SOURCES & FLASHBACK.
VAPOR-AIR MIXTURES ARE EXPLOSIVE >FLASH POINT.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT INCLUDING RUBBER
BOOTS/GLOVES/APRON & SCBA IN PRESSURE DEMAND MODE/SUPPLIED AIR
RESPIRATOR. SMALL: MOP/WIPE UP & DISPOSE OF IN DOT APPROVED WASTE
CONTAINER. LARGE: (SEE SUPP)

Handling and Storage Precautions:KEEP AWAY FROM HEAT & IGNITION
SOURCES. STORE IN COOL, DRY WELL-VENTILATED AREA FROM INCOMPATIBLE
MATERIALS. VENT CONTAINERS FREQUENTLY.
Other Precautions:ELECTRICALLY GROUND EQUIPMENT & USE ONLY NON-SPARKING
TOOLS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DON'T USE
PRESSURE TO EMPTY CONTAINER. DON'T CUT/GRIND/WELD/DRILL ON/NEAR
CONTAINER. EMPTY C ONTAINERS MAY CONTAIN RESIDUE/VAPORS.

Respiratory Protection:WEAR A NIOSH APPROVED RESPIRATOR FOR VAPOR/MIST
CONCENTRATION AT POINT OF USE, MAY BE FULL FACEPIECE/HALF MASK AIR
PURIFYING CARTRIDGE RESPIRATOR EQUIPPED FOR ORGANIC VAPOR/MISTS, A
SCBA IN PRESSURE D EMAND MODE/SUPPLIED AIR RESPIRATOR.
Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING
EMISSIONS AT POINT OF USE BELOW THE LOWEST PEL.
Protective Gloves:RUBBER
Eye Protection:CHEMICAL GOGGLES W/FULL FACEPIECE
Other Protective Equipment:LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES,
RUBBER APRON, EYEWASH, SAFETY SHOWER.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
SPILLS CONT'D: SMALL: A FULL FACEPIECE AIR PURIFYING CARTRIDGE
RESPIRATOR EQUIPPED FOR ORGANIC VAPORS. ALWAYS WEAR EYE PROTECTION.
LARGE: CONTAIN BY DIKING W/SOIL/OTHER NON-COMBUSTIBLE SORBENT
MATERIA L & PUMP INTO DOT APPROVED WASTE CONTAINERS. KEEP OUT OF
SEWERS/STORM DRAINS/SURFACE WATERS & SOIL.

Vapor Density:>1
Spec Gravity:0.81
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, TAN TO BROWN LIQUID W/CHRYSANTHEMUM-LIKE
ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS & ALKALIES.
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES.
Hazardous Decomposition Products:CO, CO2, UNIDENTIFIED ORGANIC
COMPOUNDS IN BLACK SMOKE.

Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. EMPTY CONTAINERS CAN HAVE RESIDUES, GASES & MISTS &
ARE SUBJECT TO PROPER WASTE DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.